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Lončarić, Doroteja; Movahedifar, Fahimeh; Štoček, Jakub Radek; Dračínský, Martin; Cvačka, Josef; Guan, Shanshan; Bythell, Benjamin J.; Císařová, Ivana; Masson, Eric; Kaleta, Jiří (, Chemical Science)Cucurbit[7]uril complexes aggregate into well-defined trimers in dimethyl sulfoxide in the presence of a selection of cations, as long as the host cavity is filled with a guest that leaves one carbonylated portal available for cation binding.more » « less
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Ganguly, Pritam; Bubák, Dominik; Polák, Jakub; Fagan, Patrik; Dračínský, Martin; van der Vegt, Nico F.; Heyda, Jan; Shea, Joan-Emma (, The Journal of Physical Chemistry Letters)
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Dračínský, Martin; Hurtado, Carina Santos; Masson, Eric; Kaleta, Jiří (, Chemical Communications)null (Ed.)Solvent-free mechanochemical synthesis (ball-milling) was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules (adamantane, adamantyl-1-amine hydrochloride, toluidine hydrochloride, and p -phenylenediamine dihydrochloride). Successful formation of individual inclusions was independently confirmed by one- and two-dimensional solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis represents an alternative path towards new types of cucurbit[ n ]uril/guest inclusion complexes that are not accessible due to limited solubility of the individual components.more » « less
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